Solvent Effects and Metal Ion Recognition in Several Azulenyl-Vinyl-Oxazolones

V). Separation Processes-solvent Extraction/ Ion Exchange for Metal Ions

In the hydrometallurgical processing of complex ores/ concentrates/ secondaries/ wastes, the solutions containing different non-ferrous metals are obtained during teaching the materials in acidic, ammoniacal or alkaline lixiviants. The spent solutions and effluents are also generated in different process industries and contain metallic values. Their discharge in the sewage or river is major con...

synthesis of sulfides from alcohols and thiols in solvent-freeconditions and deoxygenation of sulfoxides

کاتالیست یک سنتز جدید برای تیواترها توصیف شده است. واکنش الکل ها با آریل، هتروآریل و آلکیل تیو ل ها درحضور 1،3،5- تری آزو- 2،4،6- تری فسفرین-2،2،4،4،6،6 هگزاکلراید ((tapc به عنوان یک کاتالیست موُثر، بازده های خوب تا عالی از تیواترها را حاصل می کند. علاوه براین، واکنش تحت شرایط بدون فلز و بدون حلال پیش می رود، بنابراین یک مکمل جالب برای روش های شناخته شده سنتز تیواترها ارائه می دهد. یک مکانیسم ا...

Ion Irradiation Induced Effects in Metal Nanostructures

High resolution transmission electron microscopy (HRTEM) and Rutherford backscattering spectrometry (RBS) are used to study the ion induced effects in Au, Ag nanostructures grown on Si and thermally grown SiO2 substrates. Au and Ag films (∼ 2 nm) are prepared by thermal evaporation under high vacuum condition at room temperature (RT). These films were irradiated with MeV Au ions also at RT. Ver...

Partitioning of solvent effects and intrinsic interactions in biological recognition.

Ion solvation in liquid mixtures: effects of solvent reorganization.

Using field-theoretic techniques, we study the solvation of salt ions in liquid mixtures, accounting for the permanent and induced dipole moments, as well as the molecular volume of the species. With no adjustable parameters, we predict solvation energies in both single-component liquids and binary liquid mixtures that are in excellent agreement with experimental data. Our study shows that the ...